Tuning Phonon Dynamics for Efficient Photoelectrochemical Water Splitting

Research Project: 01.09.2025 -30.04.2026

 

 This research aims to address critical bottlenecks in photoelectrochemical (PEC) water splitting by exploring the role of phonon dynamics in improving energy efficiency of hydrogen production. PEC water splitting, a promising sustainable hydrogen production technology, faces challenges related to charge carrier recombination and energy loss. By tuning phonon dynamics, this project seeks to prolong hot-carrier lifetimes and reduce carrier-phonon scattering thereby enhancing sunlight-to-hydrogen conversion efficiency.

Key objectives include:

  • • Investigating the impact of phonon dynamics on charge carrier cooling and recombination in semiconductor materials.
  • • Engineering materials with tailored phononic properties to improve PEC performance.
  • • Correlating phonon behaviour with PEC efficiency through advanced spectroscopic and photoelectrochemical measurements. 

 

Using materials like hematite, ZnO, TiO₂, and BiVO₄, this study integrates Raman and Brillouin spectroscopy with time-resolved techniques to map phonon lifetimes and electron-phonon coupling. Collaborations with leading experts in nanomaterials and PEC characterization ensure access to cutting-edge synthesis and analytical tools.

Publications

Team Members

Ilaria Zardo
Principal Investigator

Ilaria Zardo

Aswathi Kanjampurath Sivan
Principal Investigator

Aswathi Kanjampurath Sivan

Funding

This project is funded by the Research Fund of the University of Basel for Excellent Junior Researchers.

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